Engineering QuestionsChemistry

170 solved questions with detailed explanations

121

Q.68. Which statements are True? A. In Hoffmann bromamide degradation, 4 moles of NaOH and 2 moles of Br₂ are consumed per mole of an amide B. Hoffmann bromamide reaction is not given by alkyl amides.

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122

Q.62. Consider |x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with x number of unpaired electrons from the following are: A. Sc³⁺ B

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123

Q.57. The 1st ionization enthalpy for Mg is +737 kJ/mol. The most probable estimated value of the 2nd ionization enthalpy of Mg is ______.

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124

Q.64. Identify the correct IUPAC name of hydrocarbon (x) containing three primary carbon atoms and with molar mass 72 g mol⁻¹.

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125

Q.53. is isostructural with : Choose the correct answer from the options given below:

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126

Q.60. Given below are two statements : Statement I: The number of pairs among [Ti, V], [V, Mn], [Mn, Fe] and [V, Cr] in which both ions are coloured is 3. Statement II: The number pairs among [La, Yb]

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127

Q.57. Match List-I with List-II. List-I (Reagents) A. H, Pd-BaSO B. SnCl, HCl C. CrOCl, CS D. CO, HCl, Anhyd. AlCl List-II (Reaction Name (Involving aldehydes)) I. Etard Reaction II. Rosenmund Reducti

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128

Q.51. The ratio of mass percentage (w/w) of C : H in a hydrocarbon is 12 : 1. It has two carbon atoms. The weight (in g) of formed when 3.38 g of this hydrocarbon is completely burnt in oxygen is : (

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129

Q.55. 20 mL of a solution of acetic acid required 28.4 mL of 0.1 M NaOH for its neutralization. A solution (X) was prepared by mixing 20 mL of the above acetic acid and 14.2 mL of 0.1 M NaOH solution.

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130

Q.59. Find the correct statements related to group 15 hydrides. A. Reducing nature increases from NH₃ to BiH₃ B. Tendency to donate lone pair of electrons decreases from NH₃ to BiH₃ C. The stability o

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131

Q.69. Among Fe³⁺, Pb²⁺, Cu²⁺ and Mn²⁺, identify the one that gets precipitated out while passing H₂S in presence of NH₄OH as group reagent. The highest possible oxidation state of the corresponding me

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132

Q.64. Given below are two statements : Statement-I : 2, 6-diethylcyclohexanone and 6-methyl-2-n-propylcyclohexanone are metamers. Statement-II: 2, 2, 6, 6-tetramethylcyclohexanone exhibits keto-enol t

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133

Q.51. An oxide of iron contains 69.9% iron, its empirical formula, is: (Given : Molar mass of Fe and O are 56 and 16 g mol respectively.)

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134

Q.60. Consider the metal complexes [Ni(en)] (A), [NiCl] (B) and [Ni(NH)] (C). Choose the CORRECT option by considering the number of unpaired electron present in (A), (B) and (C) respectively and the

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135

Q.52. The first and second ionization constants of a weak dibasic acid are and respectively. 0.1 mol of was dissolved in 1L of 0.1 M HCl solution. The concentration of in the resultant solution i

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136

Q.66. Given below are two statements : Statement-I : 3-phenylpropene reacts with HBr and gives secondary alkyl bromide having a chiral carbon atom as the major product. Statement-II: Aryl chlorides an

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137

Q.69. Given below are two statements : Statement-I : [Figure: Glucose anomers] are two anomers of D-(+)-glucose. Statement-II : The open chain forms of D-glucose and D-fructose contain three similar c

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138

Q.71. If 3.365 g of ethanol (l) burnt completely in a bomb calorimeter at 298.15K, the heat produced is 99.472 kJ. The |ΔH| of ethanol at 298.15 K is ______ × 10² kJ mol⁻¹. (Nearest integer) Given : S

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139

Q.62. Given below are two statements : Statement I: Vapours of the liquid with higher boiling point condense before vapours of the liquid with lower boiling points in fractional distillation. Statemen

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140

Q.74. Sucrose hydrolyses in acidic medium into glucose and fructose by first order rate law with t = 3 hour. The percentage of sucrose remaining after 6 hours is ______ (Nearest integer) (Given: log 2

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