Engineering QuestionsChemistry

170 solved questions with detailed explanations

21

Q.67. Given below are two statements : Statement-I : Heating benzamide with bromine in an ethanolic solution of sodium hydroxide will give benzylamine. Statement-II : Nitration of aniline with at 288

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22

Q.51. Match List-I with List-II. List-I Mass of substance A. 1.8 mg water B. 9.8 mg sulphuric acid C. 1.8 mg carbon D. 5.85 mg salt (NaCl) List-II Number of atoms I. 2 × 10⁻⁴ × N_A II. 1.5 × 10⁻⁴ × N_

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23

Q.72. Consider the isomers of hydrocarbon with molecular formula C₈H₁₀. These isomers do not decolourise KMnO₄ solution. These isomers are subjected to chlorination with chlorine in presence of light

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24

Q.56. When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a solvent the vapor pressure of solution was x% of vapor pressure of pure solvent. What is x% ?

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25

Q.53. Bromine trifluoride autoionizes to form BrF and BrF. The shapes of the cation and anion are respectively _______ and _______.

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26

Q.65. Complete the following reaction sequence and give the name of major product 'P'. (Major product)

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27

Q.71. The first and second ionization constants of H₂X are and respectively. The concentration of X²⁻ in 0.1 M H₂X solution is M. (Nearest Integer)

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28

Q.54. The pairs among A = [SO, CO], B = [O, F], C = [CN, CO], D = [NH, HO] and E = [MnO, CrO] that do not have similar Lewis dot structure are :

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29

Q.71. 5.33 g of CrCl₃·6H₂O, which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with AgNO₃, results in

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30

Q.56. The solubility product constants of AgCrO and AgBr are 32x and 4y respectively at 298 K. The value of can be expressed as :

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31

Q.58. is the time required for the 100% completion of the reaction while is the time required for 50% of the reaction to be completed. Which of the following option correctly represents the relation

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32

Q.73. 4.7 g of phenol is heated with Zn to give product X. If this reaction goes to 60% completion then the number of moles of compound X formed will be ______ 10 (Nearest Integer) (Given molar mass

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33

Q.64. Given below are two statements : Statement (I) : Benzyl chloride reacts faster in S1 mechanism than ethyl chloride. Statement (II) : Ethyl carbocation intermediate is less stabilized by hypercon

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34

Q.56. Match the LIST-I with LIST-II List-I Reaction A. Williamson Synthesis B. Friedel Craft Reaction C. Bromination of vinyl benzene D. Chlorination of toluene in light List-II Mechanism I. Electroph

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35

Q.68. Arrange the following compounds according to increasing order of boiling points. n-CHOH (A), n-CHNH (B), n-CH (C) and CHNHCH (D).

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36

Q.56. Given at 298 K: The in Volt at 298 K is given by :

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37

Q.51. Match List-I with List-II. List-I (Mass of substance) A. 1.8 mg water B. 9.8 mg sulphuric acid C. 1.8 mg carbon D. 5.85 mg salt (NaCl) List-II (Number of atoms) I. II. III. IV. Choose the co

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38

Q.65. Given below are four compounds: (a) n-propyl chloride (b) iso-propyl chloride (c) sec-butyl chloride (d) neo-pentyl chloride Percentage of carbon in the one which exhibits optical isomerism is:

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39

Q.67. For a closed circuit Daniell cell, which of the following plots is the accurate one at a given temperature? [Figure: Four graphs of E°cell vs time]

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40

Q.52. The species having identical radii according to the Bohr's theory are : A. H (first orbit) B. He (first orbit) C. He (second orbit) D. Li (first orbit) E. Be (Second orbit) Choose the correct an

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